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The Probabilistic Turn (1876–1884)

Olivier Darrigol

in Atoms, Mechanics, and Probability: Ludwig Boltzmann's Statistico-Mechanical Writings - An Exegesis

Published in print:
2018
Published Online:
March 2018
ISBN:
9780198816171
eISBN:
9780191853661
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780198816171.003.0005
Subject:
Physics, Atomic, Laser, and Optical Physics, History of Physics

This chapter deals with writings in which Boltzmann expressed the statistical nature of the entropy law and temporarily made the relation between entropy and combinatorial probability a basic ... More


Enthalpy and thermochemistry

Dennis Sherwood and Paul Dalby

in Modern Thermodynamics for Chemists and Biochemists

Published in print:
2018
Published Online:
August 2018
ISBN:
9780198782957
eISBN:
9780191826177
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780198782957.003.0006
Subject:
Physics, Theoretical, Computational, and Statistical Physics

Definition and mathematics of enthalpy. Definition of heat capacity at constant pressure as CP = (∂H/∂T)V. Endothermic and exothermic reactions. Role of the change in enthalpy as regards the ... More


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