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Low-Basicity and Low-Polarity Aprotic Solvents

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0007
Subject:
Physics, Condensed Matter Physics / Materials

Low-basicity and low-polarity aprotic solvents, including importantly acetonitrile and tetrahydrofuran, are poor at solvating both anions and cations. Dissociation constants are consequently very ... More


Appendices: Dissociation Constants in Methanol and Aprotic Solvents

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0009
Subject:
Physics, Condensed Matter Physics / Materials

Tables of dissociation constants are given for a wide range of substrates in the most extensively studied non-aqueous solvents, including methanol, dimethylsulphoxide, dimethylformamide, ... More


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