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The problem of polyatomic molecules

CARLO CERCIGNANI

in Ludwig Boltzmann: The Man Who Trusted Atoms

Published in print:
2006
Published Online:
January 2010
ISBN:
9780198570646
eISBN:
9780191717949
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780198570646.003.0008
Subject:
Physics, History of Physics

Polyatomic molecules created difficulties in kinetic theory from the start, with the problem of thermal capacities or specific heats. If the problem of specific heats was initially solved with the ... More


Constructing Thermal Equilibrium (1866–1871)

Olivier Darrigol

in Atoms, Mechanics, and Probability: Ludwig Boltzmann's Statistico-Mechanical Writings - An Exegesis

Published in print:
2018
Published Online:
March 2018
ISBN:
9780198816171
eISBN:
9780191853661
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780198816171.003.0003
Subject:
Physics, Atomic, Laser, and Optical Physics, History of Physics

This chapter is the first subset of a set of critical summaries Boltzmann’s writings on kinetic-molecular theory. It covers a first period in which he tried to construct the laws of thermal ... More


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