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Determination of Dissociation Constants

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0004
Subject:
Physics, Condensed Matter Physics / Materials

The determination of dissociation constants in non-aqueous and mixed-aqueous solvents is described. pH-scales, upon which the dissociation constants are based, are defined and compared with the ... More


High-Basicity Polar Aprotic Solvents

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0006
Subject:
Physics, Condensed Matter Physics / Materials

Basic polar aprotic solvents such as dimethylsulphoxide, dimethylformamide, and N-methylpyrrolidin-2-one are very poor at solvating anions, but interact strongly with cations and the proton in ... More


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