Vikas Mittal (ed.)
- Published in print:
- 2011
- Published Online:
- September 2011
- ISBN:
- 9780199581924
- eISBN:
- 9780191728853
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199581924.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
Polymer nanocomposites with practically all the commercial polymer matrices have been synthesized and nano-scale filler dispersion has been achieved with varying degrees of success. The commercial ...
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Polymer nanocomposites with practically all the commercial polymer matrices have been synthesized and nano-scale filler dispersion has been achieved with varying degrees of success. The commercial polymer nanocomposites studied to a great extent are unfortunately non-biodegradable like polyethylene, polypropylene and polystyrene etc. To a small extent, these nanocomposites are reformed or recycled into other products after one life cycle, however, the properties of such recycled materials are very poor. Therefore, subject of bio-based nanocomposites and biodegradable nanocomposites has become topic of interest in the recent years and a number of suitable bio-based and biodegradable polymer matrices have been developed and their property enhancement have been reported after the incorporation of the inorganic filler materials. These systems include poly(lactic acid), poly(butyl succinate), alginate, cellulosic plastics, gelatine, starch, soy protein based polymers, plant oil based polymers, poly(hydroxyalkanoates), bio based epoxies, etc. Various inorganic filler systems like clay, spherical particles as well as nanotubes have been incorporated in these matrices. The various properties which have been enhanced include mechanical performance, thermal properties, gas diffusion resistance, flammability, rheological performance, biodegradation etc. Though the commercial applications of these bio-nanocomposites are in infancy, but these materials have a huge commercial potential. The book provides the description of the subject as a whole, from the basic introduction to the more specific systems and advancements. The use of such nanocomposites for packaging as well as for sensors has been depicted.Less
Polymer nanocomposites with practically all the commercial polymer matrices have been synthesized and nano-scale filler dispersion has been achieved with varying degrees of success. The commercial polymer nanocomposites studied to a great extent are unfortunately non-biodegradable like polyethylene, polypropylene and polystyrene etc. To a small extent, these nanocomposites are reformed or recycled into other products after one life cycle, however, the properties of such recycled materials are very poor. Therefore, subject of bio-based nanocomposites and biodegradable nanocomposites has become topic of interest in the recent years and a number of suitable bio-based and biodegradable polymer matrices have been developed and their property enhancement have been reported after the incorporation of the inorganic filler materials. These systems include poly(lactic acid), poly(butyl succinate), alginate, cellulosic plastics, gelatine, starch, soy protein based polymers, plant oil based polymers, poly(hydroxyalkanoates), bio based epoxies, etc. Various inorganic filler systems like clay, spherical particles as well as nanotubes have been incorporated in these matrices. The various properties which have been enhanced include mechanical performance, thermal properties, gas diffusion resistance, flammability, rheological performance, biodegradation etc. Though the commercial applications of these bio-nanocomposites are in infancy, but these materials have a huge commercial potential. The book provides the description of the subject as a whole, from the basic introduction to the more specific systems and advancements. The use of such nanocomposites for packaging as well as for sensors has been depicted.
Thomas Ihn
- Published in print:
- 2009
- Published Online:
- February 2010
- ISBN:
- 9780199534425
- eISBN:
- 9780191715297
- Item type:
- chapter
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199534425.003.0006
- Subject:
- Physics, Condensed Matter Physics / Materials
This chapter discusses some of the most common fabrication methods used for the realization of semiconductor nanostructures. Top-down and bottom-up approaches are distinguished. Among the latter, ...
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This chapter discusses some of the most common fabrication methods used for the realization of semiconductor nanostructures. Top-down and bottom-up approaches are distinguished. Among the latter, self-assembled growth, growth on pre-patterned substrates, cleaved edge overgrowth, the catalytic growth of nanowires, and carbon nanotube fabrication are looked at more closely. Beyond these techniques, lateral patterning with photolithography, electron-beam lithography, and local anodic oxidation are discussed. The chapter ends with a brief description of the mechanical exfoliation of single-layer graphene sheets.Less
This chapter discusses some of the most common fabrication methods used for the realization of semiconductor nanostructures. Top-down and bottom-up approaches are distinguished. Among the latter, self-assembled growth, growth on pre-patterned substrates, cleaved edge overgrowth, the catalytic growth of nanowires, and carbon nanotube fabrication are looked at more closely. Beyond these techniques, lateral patterning with photolithography, electron-beam lithography, and local anodic oxidation are discussed. The chapter ends with a brief description of the mechanical exfoliation of single-layer graphene sheets.
E. L. Wolf
- Published in print:
- 2013
- Published Online:
- January 2014
- ISBN:
- 9780199645862
- eISBN:
- 9780191767852
- Item type:
- chapter
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199645862.003.0005
- Subject:
- Physics, Condensed Matter Physics / Materials
Micro-mechanical exfoliation of single graphene sheets from bulk mineral graphite opened the way to reliable measurements of graphene monolayer properties. The substrate supporting the monolayer ...
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Micro-mechanical exfoliation of single graphene sheets from bulk mineral graphite opened the way to reliable measurements of graphene monolayer properties. The substrate supporting the monolayer affects the measured properties. The monolayer is also sensitive to local electric fields that induce local fluctuations in charge density and Fermi energy. Methods of producing multilayer graphenes come from chemical exfoliation in strong acids, separating and oxidizing the layers. The reduction back to carbon leaves many in-plane point defects, degrading the electrical properties. Catalytic CVD on copper is a leading method for making large area, high quality robust sheets. Four transferred monolayers with chemical doping and one meter extent, have resistance as low as 40 Ω/square with high optical transparency, suitable for touch-screen application. Costs are comparable with those of conventional methods, with a flexibility/durability advantage to the graphene product.Less
Micro-mechanical exfoliation of single graphene sheets from bulk mineral graphite opened the way to reliable measurements of graphene monolayer properties. The substrate supporting the monolayer affects the measured properties. The monolayer is also sensitive to local electric fields that induce local fluctuations in charge density and Fermi energy. Methods of producing multilayer graphenes come from chemical exfoliation in strong acids, separating and oxidizing the layers. The reduction back to carbon leaves many in-plane point defects, degrading the electrical properties. Catalytic CVD on copper is a leading method for making large area, high quality robust sheets. Four transferred monolayers with chemical doping and one meter extent, have resistance as low as 40 Ω/square with high optical transparency, suitable for touch-screen application. Costs are comparable with those of conventional methods, with a flexibility/durability advantage to the graphene product.
E. L. Wolf
- Published in print:
- 2013
- Published Online:
- January 2014
- ISBN:
- 9780199645862
- eISBN:
- 9780191767852
- Item type:
- book
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/acprof:oso/9780199645862.001.0001
- Subject:
- Physics, Condensed Matter Physics / Materials
Graphene: A New Paradigm in Condensed Matter and Device Physics is a complete description of the science and applications of graphene. Graphene, the single layer of graphite, is now ...
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Graphene: A New Paradigm in Condensed Matter and Device Physics is a complete description of the science and applications of graphene. Graphene, the single layer of graphite, is now recognized as a revolutionary two-dimensional one-atom-thick material of exceedingly high electrical conductivity and tensile strength. This book reviews the developments in physics and materials science, starting in 2004 that led to Nobel Prizes in Physics, for Andre Geim and Konstantin Novoselov in 2010. The physics is unusual, offering electrons in conical bands that behave more like photons or neutrinos and, as electrical carriers, remarkably free from backscattering. Nonetheless all of these aspects have been treated, as explained in this book, using the same methods that work well for silicon, the present basis of the information technology. The book describes graphene as the first in a new class of two-dimensional materials, effectively crystalline on practical size scales up to one meter. Graphene, despite theoretical predictions of non–crystallinity of two-dimensional matter at finite temperature, is actually refractory, estimated to exist nearly to 4,900K, well above the experimentally-known sublimation point of graphite at 3,900K. The key to potential applications of graphene lies in methods of fabrication that range from chemical exfoliation of graphite crystals to chemical vapor deposition methods similar to those of the present semiconductor industry. Applications expected in future generations of digital computing technology are described in this book. These include flash memory elements, on-chip interconnects, high frequency field-effect transistors and possible tunneling switching transistors fabricated from graphene.Less
Graphene: A New Paradigm in Condensed Matter and Device Physics is a complete description of the science and applications of graphene. Graphene, the single layer of graphite, is now recognized as a revolutionary two-dimensional one-atom-thick material of exceedingly high electrical conductivity and tensile strength. This book reviews the developments in physics and materials science, starting in 2004 that led to Nobel Prizes in Physics, for Andre Geim and Konstantin Novoselov in 2010. The physics is unusual, offering electrons in conical bands that behave more like photons or neutrinos and, as electrical carriers, remarkably free from backscattering. Nonetheless all of these aspects have been treated, as explained in this book, using the same methods that work well for silicon, the present basis of the information technology. The book describes graphene as the first in a new class of two-dimensional materials, effectively crystalline on practical size scales up to one meter. Graphene, despite theoretical predictions of non–crystallinity of two-dimensional matter at finite temperature, is actually refractory, estimated to exist nearly to 4,900K, well above the experimentally-known sublimation point of graphite at 3,900K. The key to potential applications of graphene lies in methods of fabrication that range from chemical exfoliation of graphite crystals to chemical vapor deposition methods similar to those of the present semiconductor industry. Applications expected in future generations of digital computing technology are described in this book. These include flash memory elements, on-chip interconnects, high frequency field-effect transistors and possible tunneling switching transistors fabricated from graphene.
Falko P. Netzer and Claudine Noguera
- Published in print:
- 2021
- Published Online:
- April 2021
- ISBN:
- 9780198834618
- eISBN:
- 9780191872716
- Item type:
- chapter
- Publisher:
- Oxford University Press
- DOI:
- 10.1093/oso/9780198834618.003.0005
- Subject:
- Physics, Condensed Matter Physics / Materials, Particle Physics / Astrophysics / Cosmology
The novel physical and chemical properties and functionalities of two-dimensional (2-D) oxide materials are assessed. The synthesis of one unit-cell thick 2-D oxides poses particular challenges, ...
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The novel physical and chemical properties and functionalities of two-dimensional (2-D) oxide materials are assessed. The synthesis of one unit-cell thick 2-D oxides poses particular challenges, since in contrast to other 2-D materials, which can be fabricated by exfoliation of layered bulk compounds, the majority of oxides do not occur in layered bulk structures. Most 2-D oxides are therefore prepared by thin-film deposition methods on substrates. However the fabrication of free-standing quasi-2-D oxide nanosheets, with less restrictive several monolayer thickness, has been successfully achieved by wet chemical procedures. New geometry concepts and electronic properties are observed in 2-D oxides, due to quantum confinement and interface proximity effects. Atomic geometries, electronic structure, ferroic properties and catalytic behaviour of 2-D oxides are discussed, together with promising prototypical proof-of-concept experiments for prospective applications. The edge states in oxide nanoribbons, 2-D objects of limited width, and their polarity aspects are discussed.Less
The novel physical and chemical properties and functionalities of two-dimensional (2-D) oxide materials are assessed. The synthesis of one unit-cell thick 2-D oxides poses particular challenges, since in contrast to other 2-D materials, which can be fabricated by exfoliation of layered bulk compounds, the majority of oxides do not occur in layered bulk structures. Most 2-D oxides are therefore prepared by thin-film deposition methods on substrates. However the fabrication of free-standing quasi-2-D oxide nanosheets, with less restrictive several monolayer thickness, has been successfully achieved by wet chemical procedures. New geometry concepts and electronic properties are observed in 2-D oxides, due to quantum confinement and interface proximity effects. Atomic geometries, electronic structure, ferroic properties and catalytic behaviour of 2-D oxides are discussed, together with promising prototypical proof-of-concept experiments for prospective applications. The edge states in oxide nanoribbons, 2-D objects of limited width, and their polarity aspects are discussed.