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Low-Basicity and Low-Polarity Aprotic Solvents

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0007
Subject:
Physics, Condensed Matter Physics / Materials

Low-basicity and low-polarity aprotic solvents, including importantly acetonitrile and tetrahydrofuran, are poor at solvating both anions and cations. Dissociation constants are consequently very ... More


Appendices: Dissociation Constants in Methanol and Aprotic Solvents

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0009
Subject:
Physics, Condensed Matter Physics / Materials

Tables of dissociation constants are given for a wide range of substrates in the most extensively studied non-aqueous solvents, including methanol, dimethylsulphoxide, dimethylformamide, ... More


Mainly aliphatic molecules

John H. D. Eland and Raimund Feifel

in Double Photoionisation Spectra of Molecules

Published in print:
2017
Published Online:
March 2018
ISBN:
9780198788980
eISBN:
9780191830983
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780198788980.003.0007
Subject:
Physics, Condensed Matter Physics / Materials, Atomic, Laser, and Optical Physics

Double photoionisation spectra of homologous iodides and alcohols, acetonitrile, methyl mercaptan, acetaldehyde, acetone, norbornane, cyclooctatetraene, and TMMD are presented. Effects on the spectra ... More


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