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Segmental Orientation

Burak Erman and James E. Mark

in Structures and Properties of Rubberlike Networks

Published in print:
1997
Published Online:
November 2020
ISBN:
9780195082371
eISBN:
9780197560433
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195082371.003.0013
Subject:
Chemistry, Materials Chemistry

Segmental or molecular orientation refers to the anisotropic distribution of chain-segment orientations in space, due to the orienting effect of some external agent. In the case of uniaxially ... More


Intermolecular Effects: II. Constraints along Network Chains

Burak Erman and James E. Mark

in Structures and Properties of Rubberlike Networks

Published in print:
1997
Published Online:
November 2020
ISBN:
9780195082371
eISBN:
9780197560433
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195082371.003.0006
Subject:
Chemistry, Materials Chemistry

In the constrained-junction model presented in chapter 3, intermolecular correlations were assumed to suppress the fluctuations of junctions. According to this model, the elastic free energy of a ... More


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