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Intermolecular Effects: I. The Constrained-Junction Model

Burak Erman and James E. Mark

in Structures and Properties of Rubberlike Networks

Published in print:
1997
Published Online:
November 2020
ISBN:
9780195082371
eISBN:
9780197560433
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195082371.003.0005
Subject:
Chemistry, Materials Chemistry

The classical theories of rubber elasticity presented in chapter 2 are based on a hypothetical chain which may pass freely through its neighbors as well as through itself. In a real chain, however, ... More


Networks with Semiflexible Chains and Networks Exhibiting Strain-Induced Crystallization

Burak Erman and James E. Mark

in Structures and Properties of Rubberlike Networks

Published in print:
1997
Published Online:
November 2020
ISBN:
9780195082371
eISBN:
9780197560433
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195082371.003.0014
Subject:
Chemistry, Materials Chemistry

Classical theories of rubber elasticity are based on models of flexible polymer chains that are sufficiently long to exhibit Gaussian behavior as described in chapter 1 and in appendix F. ... More


Calculations and Simulations

Burak Erman and James E. Mark

in Structures and Properties of Rubberlike Networks

Published in print:
1997
Published Online:
November 2020
ISBN:
9780195082371
eISBN:
9780197560433
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195082371.003.0010
Subject:
Chemistry, Materials Chemistry

The classical theories of rubber elasticity are based on the Gaussian chain model. The only molecular parameter that enters these theories is the mean-square end-to-end separation of the chains ... More


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