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Elastomeric Networks

James E. Mark, Dale W. Schaefer, and Gui Lin

in The Polysiloxanes

Published in print:
2015
Published Online:
November 2020
ISBN:
9780195181739
eISBN:
9780197562321
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195181739.003.0009
Subject:
Chemistry, Polymer Chemistry

Gelation is the cross-linking process that leads to the network structures required for rubberlike elasticity. In some cases, gelation can be reversible. There have been numerous studies involving ... More


Polysiloxanes and Related Polymers

James E. Mark, Harry R. Allcock, and Robert West

in Inorganic Polymers

Published in print:
2005
Published Online:
November 2020
ISBN:
9780195131192
eISBN:
9780197561454
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195131192.003.0008
Subject:
Chemistry, Polymer Chemistry

At the present time, polysiloxanes are unique among inorganic and semi-inorganic polymers. They have been the most studied by far, and are the most important with regard to commercial applications. ... More


Model Elastomers

Burak Erman and James E. Mark

in Structures and Properties of Rubberlike Networks

Published in print:
1997
Published Online:
November 2020
ISBN:
9780195082371
eISBN:
9780197560433
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195082371.003.0012
Subject:
Chemistry, Materials Chemistry

Until quite recently, there was relatively little reliable quantitative information on the relationship of stress to structure, primarily because of the uncontrolled manner in which elastomeric ... More


Surfaces

James E. Mark, Dale W. Schaefer, and Gui Lin

in The Polysiloxanes

Published in print:
2015
Published Online:
November 2020
ISBN:
9780195181739
eISBN:
9780197562321
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195181739.003.0008
Subject:
Chemistry, Polymer Chemistry

Because of the great importance of the surface properties of the polysiloxanes, this topic is treated separately in this chapter. Hydrophobic polysiloxanes having simple aliphatic or aromatic side ... More


Small-Angle Neutron Scattering

Burak Erman and James E. Mark

in Structures and Properties of Rubberlike Networks

Published in print:
1997
Published Online:
November 2020
ISBN:
9780195082371
eISBN:
9780197560433
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195082371.003.0016
Subject:
Chemistry, Materials Chemistry

Small-angle neutron scattering (SANS) experiments from networks were initiated by Benoit and collaborators in the mid-1970s. Currently, SANS is an important major technique used in studying network ... More


Swelling of Networks

Burak Erman and James E. Mark

in Structures and Properties of Rubberlike Networks

Published in print:
1997
Published Online:
November 2020
ISBN:
9780195082371
eISBN:
9780197560433
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780195082371.003.0008
Subject:
Chemistry, Materials Chemistry

In the preceding chapter, the stress-strain behavior of networks was described for the case where the swollen network was assumed to be a thermodynamically closed system (such that solvent ... More


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