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Acids and Bases: Solvent Effects on Acid-Base Strength

Brian G. Cox

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
book
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.001.0001
Subject:
Physics, Condensed Matter Physics / Materials

Acids and bases are ubiquitous in chemistry. Our understanding of them, however, is dominated by their behaviour in water. Transfer to non-aqueous solvents leads to profound changes in acid-base ... More


Static Solvent Effects, Transition-State Theory

Niels Engholm Henriksen and Flemming Yssing Hansen

in Theories of Molecular Reaction Dynamics: The Microscopic Foundation of Chemical Kinetics

Published in print:
2018
Published Online:
November 2018
ISBN:
9780198805014
eISBN:
9780191843129
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/oso/9780198805014.003.0010
Subject:
Physics, Atomic, Laser, and Optical Physics

This chapter discusses static solvent effects on the rate constant for chemical reactions in solution. It starts with a brief discussion of the thermodynamic formulation of transition-state theory. ... More


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