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Acids and Bases: Solvent Effects on Acid-Base Strength

Brian G. Cox

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
book
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.001.0001
Subject:
Physics, Condensed Matter Physics / Materials

Acids and bases are ubiquitous in chemistry. Our understanding of them, however, is dominated by their behaviour in water. Transfer to non-aqueous solvents leads to profound changes in acid-base ... More


Acid–Base Equilibria and Salt Formation

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0008
Subject:
Physics, Condensed Matter Physics / Materials

Acid–base equilibria involving salt formation and the generation of reactive intermediates, such as enolates, are discussed. The absence of the solvated proton in the equilibria means that, in ... More


Protic solvents

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0005
Subject:
Physics, Condensed Matter Physics / Materials

Protic solvents have hydrogen bound directly to electronegative atoms, such as oxygen or nitrogen. They are characterized by their ability to form strong hydrogen bonds with suitable acceptors, ... More


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