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Acids and Bases: Solvent Effects on Acid-Base Strength

Brian G. Cox

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
book
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.001.0001
Subject:
Physics, Condensed Matter Physics / Materials

Acids and bases are ubiquitous in chemistry. Our understanding of them, however, is dominated by their behaviour in water. Transfer to non-aqueous solvents leads to profound changes in acid-base ... More


Relaxation and Kinetics in Shock Tubes and Shock Tunnels

Raymond Brun

in Introduction to Reactive Gas Dynamics

Published in print:
2009
Published Online:
May 2009
ISBN:
9780199552689
eISBN:
9780191720277
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199552689.003.0014
Subject:
Physics, Theoretical, Computational, and Statistical Physics

The first part of this chapter presents experimental data on vibrational relaxation times and vibrational populations obtained in shock tubes and shock tunnels. The corresponding methods of ... More


Acid–Base Equilibria: Quantitative Treatment

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0002
Subject:
Physics, Condensed Matter Physics / Materials

Quantitative treatment of acid–base behaviour is presented, including the definition of acids, bases, and dissociation constants, and the important relationships between solution pH, acid strength, ... More


Appendices: Dissociation Constants in Methanol and Aprotic Solvents

Brian G. Cox

in Acids and Bases: Solvent Effects on Acid-Base Strength

Published in print:
2013
Published Online:
May 2013
ISBN:
9780199670512
eISBN:
9780199670512
Item type:
chapter
Publisher:
Oxford University Press
DOI:
10.1093/acprof:oso/9780199670512.003.0009
Subject:
Physics, Condensed Matter Physics / Materials

Tables of dissociation constants are given for a wide range of substrates in the most extensively studied non-aqueous solvents, including methanol, dimethylsulphoxide, dimethylformamide, ... More


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